Evaluation of the Shielding Design of the Fuel Handling and Storage System in the Prototype FBR Monju

Electrochemical studies on [UO 2 (DMF) 5 ] 2+ , UO 2 (acac) 2 DMF, and UO 2 (salen)DMF (DMF=N ,Ndimethylformamide, acac=acethylacetonate, and salen=N ,N-disalicylidene-ethylenediaminate) complexes in DMF containing tetrabutylammonium perchlorate as supporting electrolyte have been carried out by using cyclic voltammetry to compare the stabilities of the reduction products of U(VI) complexes with unidentate or multidentate ligands. The [UO 2 (DMF) 5 ] 2+ , UO 2 (acac) 2 DMF, and UO 2 (salen)DMF complexes were found to be quasi-reversibly reduced to U(V) species. The formal redox potentials (E o , vs. ferrocene/ferrocenium) for the U(VI)/U(V) couple were determined to be −0.89 V for [UO 2 (DMF) 5 ] 2+ , −1.47 V for UO 2 (acac) 2 DMF, and −1.67 V for UO 2 (salen)DMF. The U(V) species formed in the reduction of [UO 2 (DMF) 5 ] 2+ complex is not stable and further reduced to UO 2 , while those generated in the reduction of UO 2 (acac) 2 DMF and UO 2 (salen)DMF complexes can exist stably in DMF.

show abstract

Electrochemical Studies on [UO₂(DMF)₅](CIO₄)₂, UO₂(acac)₂DMF, and UO₂(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Kim

Tomiyasu

Ikeda

2002

Journal of Nuclear Science and Technology

View full text Add to dashboard Cite

show abstract

Electrochemical Studies on [UO2(DMF)5](ClO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N, N-dimethylformamide, acac=acetylacetonate, salen=N, N'-disalicylideneethylenediaminate) Complexes in DMF.

KIM

Tomiyasu

Ikeda

2002

J. Nucl. Sci. Technol.

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Evaluation of the Shielding Design of the Fuel Handling and Storage System in the Prototype FBR Monju

Cited by 2 publications

References 3 publications

Electrochemical Studies on [UO₂(DMF)₅](CIO₄)₂, UO₂(acac)₂DMF, and UO₂(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Electrochemical Studies on [UO₂(DMF)₅](CIO₄)₂, UO₂(acac)₂DMF, and UO₂(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Electrochemical Studies on [UO2(DMF)5](ClO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N, N-dimethylformamide, acac=acetylacetonate, salen=N, N'-disalicylideneethylenediaminate) Complexes in DMF.

Contact Info

Product

Resources

About

Evaluation of the Shielding Design of the Fuel Handling and Storage System in the Prototype FBR Monju

Cited by 2 publications

References 3 publications

Electrochemical Studies on [UO2(DMF)5](CIO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Electrochemical Studies on [UO2(DMF)5](CIO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Electrochemical Studies on [UO2(DMF)5](ClO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N, N-dimethylformamide, acac=acetylacetonate, salen=N, N'-disalicylideneethylenediaminate) Complexes in DMF.

Contact Info

Product

Resources

About

Electrochemical Studies on [UO₂(DMF)₅](CIO₄)₂, UO₂(acac)₂DMF, and UO₂(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF

Electrochemical Studies on [UO₂(DMF)₅](CIO₄)₂, UO₂(acac)₂DMF, and UO₂(salen)DMF (DMF=N,N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF