2021
DOI: 10.1108/rpj-12-2020-0309
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Evaluation of UV post-curing depth for homogenous cross-linking of stereolithography parts

Abstract: Purpose During post-processing of stereolithography photopolymers, the limited penetration depth of ultraviolet (UV) light can lead to inhomogeneous cross-linking. This is a major problem in part design for industrial applications as this creates uncertainty regarding the mechanical load capacity. Therefore, this paper aims to present an experimental method to measure the post-curing depth in stereolithography photopolymers. Design/methodology/approach Printed specimens made from urethane acrylate photopolym… Show more

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Cited by 9 publications
(9 citation statements)
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“…The degree of cure (DoC) is a crucial factor for the final properties of the material, especially for chain‐growth polymerization such as UV‐curing resin systems where the network is not fully formed until the late stages of curing. The DoC depends on factors such as oxygen inhibition, [ 44 ] photoinitiator and pigment concentration, [ 45 ] or monomer functionality [ 46 ] and can lead to formulations with uncured monomers and cure gradients within the sample. The degree of cure was determined by Raman spectroscopy [ 47,48 ] which, in contrast to IR spectroscopy, is more sensitive to homo‐nuclear bonds such as the CC double bond in the vinyl ester group.…”
Section: Resultsmentioning
confidence: 99%
“…The degree of cure (DoC) is a crucial factor for the final properties of the material, especially for chain‐growth polymerization such as UV‐curing resin systems where the network is not fully formed until the late stages of curing. The DoC depends on factors such as oxygen inhibition, [ 44 ] photoinitiator and pigment concentration, [ 45 ] or monomer functionality [ 46 ] and can lead to formulations with uncured monomers and cure gradients within the sample. The degree of cure was determined by Raman spectroscopy [ 47,48 ] which, in contrast to IR spectroscopy, is more sensitive to homo‐nuclear bonds such as the CC double bond in the vinyl ester group.…”
Section: Resultsmentioning
confidence: 99%
“…[4][5][6] In contrast, the ultraviolet (UV) light curing method can effectively reduce air pollution and energy consumption but this method can be only used to cure a thin-layered thermoset due to the weak penetration capability of UV light. 7,8 Among these methods, frontal polymerization (FP) is a self-sustaining curing process that relies on the heat released by polymerization exothermicity when in forming monomers to polymers, accompanied by a continuously propagating polymerization front, [9][10][11][12][13] realizing curing the epoxy resin within minutes.…”
Section: Introductionmentioning
confidence: 99%
“…Additive manufacturing (AM), also known as rapid prototyping or three-dimensional (3D)-printing, is a novel manufacturing method based on layer-by-layer fabrication (Hui et al , 2021; Bártolo and Gibson, 2011). The first commercial AM machine was stereolithography and used ultraviolet rays in 1987 (Bártolo and Gibson, 2011; Schlotthauer et al , 2021). Filament deposition method, solid ground curing and planer layering were three commercial models with different working procedures presented in 1991 (Gibson et al , 2021; Wohlers and Gornet, 2014).…”
Section: Introductionmentioning
confidence: 99%