An extensive study for Langmuir monolayer collapse is carried out to explore the generality of classification of their crack patterns (E. Hatta et al. Eur. Phys. J. 1999, B11, 609) and to analyze crack kinetics in the anisotropic cracks. Upon compression of fatty acid monolayers beyond the collapse pressure three classes of fracture patterns, a surface roughening, random crack network, or anisotropic fracture, can be observed depending on chain length of the fatty acid, pH value, and ion concentration of the subphase. A statistical characterization of the anisotropic crack growth of Langmuir monolayer fracture is presented. Anisotropic cracks grow on a Co 2+ water subphase as quasi-periodic modulations, branching off previously formed cracks, interrupted by the coalescence of modulation cracks. Slight changes in pH and concentration of Co 2+ ions in the subphase cause drastic changes of the modulation crack coalescence rate. We suggest, that differences in the viscoelastic nature of the monolayer are the main causes for the three types of crack growth scenaria.In soft condensed matter already moderate external stress may lead to nonlinear response of the material. Spontaneous and strongly correlated, dynamic collective behavior originating in the internal degrees of freedom of the constituent molecules give rise to a rich variety of nonlinear physical and chemical effects. 1 Fracture of soft condensed matter such as gels, 2 vesicles, 3 colloidal suspensions, 4 Langmuir monolayers, 5-9 and foams 10 result in various fracture patterns and spatio temporal characteristics.Different material properties in ordered and disordered matter govern the formation, 11 evolution, 12 and coalescence 13 of cracks. In solids, the simplest model is that of the competition of stress release versus the creation of surface energy (Griffith criterion 11 ), which governs the formation of a crack. It usually works well, because the region of large deformation and hence nonlinear stress-strain relationship is restricted to a small area near the tip of the crack. In soft condensed matter large deformation can exist in a macroscopic region ranging far away from the tip. It is therefore not surprising to observe new types of crack growth unexplored in solid-state materials. As the nonlinear material parameters in the constitutive equations become more important, there are several ways in which a system can change its dynamical behavior. One of the major experimental problems in following the crack dynamics arises due to the time scale on which cracking occurs in solid-state material. Usually, a crack alternates between rapid motion and arrest, and it is difficult to resolve the evolution of a crack growth. We will show that promising systems to overcome such problems are Langmuir monolayers. 14 Langmuir monolayers may crack, when compressed beyond the collapse pressure, where the two-dimensional arrangement of molecules at the air/water interface becomes unstable and the molecules start to explore the third dimension. Different phases, with...