Understanding noncircular deposition patterns can offer broad applications; however, the phenomena have not been thoroughly studied. We experimentally investigate particle self-assembly of microspherical polystyrene particle-laden sessile droplets dried on a micropyramid cavity substrate. The particle sizes and concentrations in the droplets are found to modify the inner particle deposition with the octagonal perimeter. The droplets with mass concentrations of 0.5% and higher evaporate with the pinned contact lines. The capillary flow flushes the 3 µm particles to the contact line and creates octagonal outer-ring patterns. The 10 µm particles are more evenly distributed in the depositions of the dried droplets. However, at a high mass concentration of 2.6%, the particles adsorbed at the droplet liquid-air interface form an agglomerate and deposit toward the centerline, leading to the crater-shaped pattern. Higher concentrations provoke the thicker octagonal outer-ring depositions regardless of the particle sizes in the droplets. The findings could inspire applications to control noncircular wetting and drying of particle-laden sessile droplets.