We report the first demonstration of the axialization of laser cooled ions in a Penning trap. Axialization involves the application of a small radial quadrupole drive which couples the cyclotron and magnetron motions. This enhances the laser cooling, allowing tighter confinement of the ions to the central axis of the trap than is otherwise possible. Using an intensified charge-coupled device (ICCD) camera we have imaged the axialization process for the first time. For a single ion, we recorded a large decrease of the magnetron amplitude corresponding to a reduction in ion temperature of approximately 2 orders of magnitude to an upper limit of order 10 mK. We have discovered dynamics specific to the laser cooled system which depend critically on the axial drive frequency and amplitude. DOI: 10.1103/PhysRevLett.89.093003 PACS numbers: 32.80.Pj, 03.67.Lx, 41.20.-q, 42.50.Vk With the growing interest in quantum information processing there has been an increasing need to develop technology which might enable the implementation of the ideas proposed. The uniquely stable and isolated environment of the ion trap makes it an ideal tool for the investigation of quantum phenomena; indeed, ion traps have been placed at the forefront of advances in the area of quantum information science [1]. Recent experiments include the entanglement of four trapped ions, the building of a CNOT gate and quantum state engineering using a single particle [2][3][4].Very low temperatures can be reached in ion traps using laser cooling, but the minimum temperature can be limited by the nature of the trapping method itself. The two most widely used types of ion trap are the Paul (radio frequency) trap and the Penning trap [5]. For radial confinement, the former uses an electric field oscillating at a radio frequency, while the latter uses a static magnetic field. This means that in the Paul trap the ion motion is simple harmonic in all directions but in the radial plane of the Penning trap the action of the combined electric and magnetic fields results in a more complex orbital motion: a superposition of two rotations, the magnetron and the cyclotron rotations.Until now much work in the area of quantum information science has focused on the use of linear Paul traps which allow the preparation of stationary strings of ions and strong confinement to the Lamb-Dicke regime [1]. Unfortunately, the low temperature limit of the Paul trap can be affected by the ''micromotion'' of the trapped ions, which arises as a result of the trapping field and cannot be completely avoided. The Penning trap has no such limitation [5]. However, the nature of the motion in the radial plane of the Penning trap complicates the laser cooling process [6,7]. Specifically, it is difficult to achieve small magnetron radii. Problems arise because the magnetron motion is unstable: its total energy is negative so energy must be supplied in order to reduce the magnetron radius.Three frequencies govern the motion of ions in a Penning trap. The first is ! z , which describes th...