2022
DOI: 10.26434/chemrxiv-2022-jbc9n
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Evidence for Ligand- and Metal-Centered Reduction in Polypyridyl Dicarboxylate Complexes of Ru(II) and U(VI)

Abstract: Polypyridyl dicarboxylates have been established as oxidatively robust ligands capable of effectively binding heavy metals, but the reductive electrochemical properties of complexes supported by these ligands have not been explored to date. Here, the redox properties of Ru(II) and uranyl(VI) (UO22+) complexes of 2,2′-bipyridyl-6,6′-dicarboxylate (bdc), 2,2′:6′,2″-terpyridyl-6,6″-dicarboxylate (tdc), and 4′-phenyl-2,2′:6′,2″-terpyridyl-6,6″-dicarboxylate (Phtdc) have been investigated, revealing that these liga… Show more

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“…A preprint reflecting a preliminary version of the findings reported here was posted to a preprint server. 71…”
Section: Author Contributionsmentioning
confidence: 99%
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“…A preprint reflecting a preliminary version of the findings reported here was posted to a preprint server. 71…”
Section: Author Contributionsmentioning
confidence: 99%
“…were supported by a U.S. National Science Foundation Research Traineeship (NRT) at the University of Kansas (DGE-1922649). A preprint reflecting a preliminary version of the findings reported here was posted to a preprint server …”
mentioning
confidence: 99%