1966
DOI: 10.1021/ac60234a026
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Evidence for Turbulence and Coupling in Chromatographic Columns.

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Cited by 84 publications
(27 citation statements)
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“…N depends only on the particle-to-column volume ratio. The total surface area available for adsorption inside the column, S( ), is given by: (19) where S ads is the surface area available within a fully porous particle. The elution volume under linear conditions is:…”
Section: Decreasing the Shell Thicknessmentioning
confidence: 99%
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“…N depends only on the particle-to-column volume ratio. The total surface area available for adsorption inside the column, S( ), is given by: (19) where S ads is the surface area available within a fully porous particle. The elution volume under linear conditions is:…”
Section: Decreasing the Shell Thicknessmentioning
confidence: 99%
“…Parish suggested using beads of cross-linked polystyrene bearing ion-exchange groups in a shallow surface layer to separate metal ions [5]. Knox recommended the use of thin films of the stationary liquid phase in liquid-liquid chromatography (LLC) [6]. Horváth and Lipsky suggested the use of pellicular (i.e., thin-skin) particles instead of fully porous particles as packing materials for chromatographic columns and demonstrated the value of the concept by reporting important analytical results in the ion-exchange analysis and/or the purification of nucleosides [7,8].…”
Section: Introductionmentioning
confidence: 99%
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“…The idea of using spherical particles as templates for the preparation of monolithic rods of dimensions and physical stability suitable for chromatographic application was first generated in 1966 by John Knox, who proposed an “inverse column” in which the stationary phase structure had the same shape as the mobile phase (gas phase) in the particle packed column 41. Knox stated how such a structure could be made “by filling a column with beads of some low melting point substance, fusing the points of contact, filling the gas space with a thermosetting resin, and, after curing, melting out the original beads”.…”
Section: Introductionmentioning
confidence: 99%
“…The diffusion coefficient D,, the viscosity of the eluent q. and the capacity factor K are given standard values in eqs. (5) and (6). The remaining five parameters are not independent of each other.…”
Section: Hplc Optimizationmentioning
confidence: 99%