2010
DOI: 10.1021/ja908707a
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Evidence of Double-Walled Al−Ge Imogolite-Like Nanotubes. A Cryo-TEM and SAXS Investigation

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Cited by 60 publications
(86 citation statements)
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“…11 This leads to the synthesis of concentrated (molar) suspensions of single-or double-walled (DW) aluminogermanate nanotubes with larger external diameters, typically ~ 4 nm. 9,12 More recently, Fe-doped INT have also been explored by isomorphic substitution of Al…”
Section: Introductionmentioning
confidence: 99%
“…11 This leads to the synthesis of concentrated (molar) suspensions of single-or double-walled (DW) aluminogermanate nanotubes with larger external diameters, typically ~ 4 nm. 9,12 More recently, Fe-doped INT have also been explored by isomorphic substitution of Al…”
Section: Introductionmentioning
confidence: 99%
“…The growth mechanisms of these nanotubes were investigated using several complementary techniques, including transmission electronic microscopy (TEM) and dynamic light scattering (DLS) (Yang et al, 2008). Moreover, improved protocols and synthesis of aluminogermanate analogues (Al 2 GeO 7 H 4 ) with higher electronic density has facilitated characterization of mechanisms involved in the formation of imogolite type structures (Levard et al, 2008;Levard et al, 2011;Maillet et al, 2010;Maillet et al, 2011;Mukherjee et al, 2005;Mukherjee et al, 2007;Wada and Wada, 1982). For the first time, models of Ge-imogolite precursors (commonly referred to as proto-imogolites) were thus proposed that consist of roof tile shaped nanoparticles, up to 5 nm in size, with Ge vacancies and varying curvatures .…”
Section: Introductionmentioning
confidence: 99%
“…Because of the unique physicochemical characteristics of this IONt, various synthetic processes have been developed [9,[11][12][13][14][15], reinforcing its industrial applications. It is used mainly as an adsorbent and catalytic support, with projected nanotechnological applications that increase its range of use at the industrial level [16][17][18][19][20]. The synthesis of imogolite involves a first step in which basic hydrolysis of the Si and Al precursors takes place, followed by polymerization at 95°C for a period of approximately five days during which the tubular structure is formed and the superficial active sites are modified [13,21].…”
Section: Introductionmentioning
confidence: 99%