Shear thickening polishing technology using non-Newtonian polishing uid is a low-cost, low-damage polishing method for the ultra-precision machining of complex curved surfaces. However, the shortcomings of traditional shear thickening polishing uid in polishing e ciency and uid viscosity controllability limit its further application., a novel weak magnetic eld-assisted shear thickening polishing uid (WMFA-STPF) containing carbonyl iron particles (CIPs) is presented in this study, which utilizes its weak magnetorheological effect to strengthen the shear thickening phenomenon. The rheological characteristics of the WMFA-STPF samples were investigated. The results show that WMFA-STPF has good uidity in the low shear rate range and better thickening characteristics in the working shear rate range. In order to verify the high e ciency, high quality and high uniformity polishing ability of the weak magnetic eld-assisted shear thickening polishing technology for the spherical surface of zirconia ceramic workpiece, the contrast polishing experiment was designed and nished. The experimental results show that the weak magnetic eld-assisted thickening effect can achieve high e ciency and high quality polishing of hard and brittle ceramics. After 75 min polishing, the surface damage was effectively improved and eliminated, the surface quality and uniformity were greatly improved, and the material removal rate reached 7.82 μm/h, increased by 156%.