2019
DOI: 10.1016/j.chemgeo.2018.07.011
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Evolution of chalcophile elements in the magmas of the Bonin Islands

Abstract:  Chalcophile and trace metal history of boninite series melts tracked in silicate melt inclusions across an extensive compositional range (>18 to <0.5 wt. % MgO)  Boninite series melts saturate in sulfide despite parental magmas depleted in S  Direct evidence of co-precipitation of magnetite and sulfide linked to changes in V and Cu previously inferred as sulfide/magnetite saturation

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Cited by 15 publications
(13 citation statements)
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“…The sulfur contents of all but three FAB glasses (the two enriched FAB and the FAB‐related andesite) appear to be controlled by incompatibility during crystal fractionation (Figure 5c, and see S vs. MgO in supplement), indicating that there has not been significant sulfur loss to a volatile phase (Figure 5c). In contrast, the boninite glasses have lower sulfur contents (<200 ppm), similar to those reported in melt inclusions and seafloor glass from the nearby Bonin Islands (Figure 5c, Valetich et al., 2019).…”
Section: Discussionsupporting
confidence: 81%
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“…The sulfur contents of all but three FAB glasses (the two enriched FAB and the FAB‐related andesite) appear to be controlled by incompatibility during crystal fractionation (Figure 5c, and see S vs. MgO in supplement), indicating that there has not been significant sulfur loss to a volatile phase (Figure 5c). In contrast, the boninite glasses have lower sulfur contents (<200 ppm), similar to those reported in melt inclusions and seafloor glass from the nearby Bonin Islands (Figure 5c, Valetich et al., 2019).…”
Section: Discussionsupporting
confidence: 81%
“…Existing solubility models calibrated using experimental data (e.g., D‐COMPRESS; Burgisser et al., 2015) predict that a silicate melt with H 2 O and CO 2 contents broadly similar to that of the boninite glasses (∼2 wt % H 2 O, ∼50 ppm CO 2 ) will be vapor saturated with ∼1,700 ppm sulfur at ∼760 bars total pressure, and that sulfur concentration is not predicted to decrease below 500 ppm until pressures lower than 50 bars. On the other hand, low sulfur (i.e., <200 ppm) and moderate H 2 O contents (i.e., ≥2 wt%) in silicate glasses have been observed in subduction settings by others (Brounce et al., 2016; Davis et al., 1991; Jenner et al., 2010; Rasmussen et al., 2018) including in boninitic magmas (Cooper et al., 2010; Valetich et al., 2019). These studies produce evidence both for (Cooper et al., 2010; Rasmussen et al., 2018) and against (Brounce et al., 2016; Valetich et al., 2019) high‐pressure sulfur degassing, and in sum, describe significant uncertainty in the factors that control sulfur mobility during low pressure differentiation in subduction settings.…”
Section: Discussionmentioning
confidence: 96%
“…Thus, the H 2 O concentrations of boninite series glasses (and the E‐FAB discussed above) reflect some degree of degassing prior to and during eruption on the ocean floor as well as providing evidence that all slab melts involved in boninite genesis were water‐rich. This degassing likely caused magmas also to lose S, although the low S concentrations in boninites may also reflect strong prior depletion of the mantle source (Valetich et al., 2019).…”
Section: Discussionmentioning
confidence: 99%
“…Given the compositional zonation of the crystalline phases, and the uncertainty of establishing polyphase, heterogeneous equilibria, detailed thermobarometry (via a relevant reaction that includes 56 , boninite 20,67,68 , FAB of Izu-Bonin-Mariana 11,54,55 and literature cited in ref. 19 .…”
Section: Discussionmentioning
confidence: 99%