“…Since the discovery and characterization of graphene, [1,2] the novel two-dimensional (2D) materials, especially for monoelemental 2D materials, have been the subject of an increasing area of research due to their exotic non-trivial topological properties and potential applications. [3][4][5][6][7][8][9][10] In the periodic table, most of 2D monoelemental materials, consisting of the elements in the main group of IIIA, IVA, and VA, have been successfully prepared, such as borophene, [11][12][13][14] silicene, [15][16][17] antimonene, [18][19][20][21] bismuthine, [5,22,23] and so on. [24][25][26] Among them, the 2D materials consisted of heavy elements have been predicted as topological insulators with enhanced bulk gap and nontrivial edge state due to their strong spin-orbit coupling (SOC).…”