The
third-generation semiconductors are the cornerstone of the
power semiconductor leap forward and have attracted much attention
because of their excellent properties and wide applications. Meanwhile,
femtosecond laser processing as a convenient method further improves
the performance of the related devices and expands the application
prospect. In this work, an approximate 3 times improvement of the
internal quantum efficiency (IQE) and a 5.5 times enhancement of the
photoluminescence (PL) intensity were achieved in the GaN film prepared
using a one-step femtosecond laser fabrication method. Three types
of final micro/nanostructures were found with different femtosecond
laser fluences, which could be attributed to the decomposition, melting,
bubble nucleation, and phase explosion of GaN. The mechanisms of the
microbump structure formation and enhancement of IQE were studied
experimentally by the time-resolved reflection pump–probe technique,
X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Simulations
for the laser–GaN interaction have also been performed to ascertain
the micro/nanostructure formation principle. These results promote
the potential applications of femtosecond lasers on GaN and other
wide band gap semiconductors, such as UV-light-emitting diodes (LEDs),
photodetectors, and random lasers for use in sensing and full-field
imaging.