Rapidly increasing global energy demand resulting from
the growing
population and worldwide development has increased the consumption
of limited fossil fuel. The usage causes severe environmental deterioration
by CO2 emission, which has sparked interest in finding
green, renewable, and sustainable alternative sources of energy. Bio-oil,
derived from several biomasses via liquefaction, is a promising candidate
to replace fossil fuels. Turkey’s land (27%) is covered with
forested areas (consisting of mostly oak trees). Therefore, it has
great potential for cheap lignocellulosic feedstock forest residues
from industrial applications and harvesting. In the present study,
the thermal liquefaction of oak wood particles (OWP) was performed
using various solvents in addition to water, namely, ethanol, 1-butanol,
and 1,4-dioxane. The experiments were carried out in a batch reactor
for 1 and 2 h residence times at different temperatures (210, 240,
and 270 °C). Bio-oil samples obtained at 270 °C and a 1
h residence time determined as optimum conditions were analyzed with
TGA, CHNS elemental analysis, FTIR, and GC–MS. 1,4-Dioxane
showed the best performance in yielding the maximum bio-oil with 51.8%
at those conditions. The higher heating values of the bio-oils ranged
from 22.1 to 35 MJ/kg. Phenolic groups were the predominant components
of bio-oil produced from OWP, while the intensity of alcohols, ketones,
and acids varied based on used solvents. Based on energy recovery
calculations, the enhancement of pristine OWP’s energy efficiency
depended on bio-oil yield, and quality was confirmed for all solvent
types (1,4-dioxane > 1-butanol > water > ethanol).