Nano size Mg x Co 1−x Fe 2 O 4 (x = 0, 0.2, 0.4, 0.6, 0.8 and 1.0) ferrites have been prepared using sol gel method and characterized using i.r., TEM, XRD, magnetic and Mössbauer spectral studies. The particle size of as obtained samples was found to be ∼6 nm, which increases up to ∼80 nm after annealing at 1,000 • C. The saturation magnetization decreases from 80.0-27.5 emu/g on increasing the Mg 2+ ions after annealing at 1,000 • C due to the diamagnetic behaviour of the Mg 2+ ions. Room temperature (RT) Mössbauer spectra (MS) of as obtained samples exhibit a broad doublet, suggesting super paramagnetic nature of the sample. However, annealed samples exhibited a broad sextet, resolved into two sextets, corresponding to tetrahedrally and octahedrally coordinated Fe cations.