Evolution of x-ray resonance Raman scattering into x-ray fluorescence from the excitation of xenon near theL3edge

Rydberg-Resolved Resonant Inelastic Soft X-Ray Scattering: Dynamics at Core Ionization Thresholds

“…The onset o f the continua is modeled by a step function broadened by a Lorentzian to account for the lifetime width and norm alized to achieve a flat intensity level, and the lifetim e-broadened emission following continuum excitation is assum ed to appear at threshold. This model is essentially identical to the model presented by Tulkki and Aberg [11], which has earlier been confirmed [21] at high energies without Rydberg resolution.…”

Studies of fluorescence and Auger decay following inner-shell photoionization

“…Emitted X-rays were dispersed using a Ge (2 2 0) curved-crystal monochromator and detected on a position-sensitive proportional counter. Further experimental details are available elsewhere (MacDonald et al, 1995). Fig.…”

Resonant inelastic x-ray scattering of methyl chloride at the chlorine K edge

“…It has been shown that polarized x-ray-emission spectroscopy allows direct determination of the symmetries of occupied/unoccupied valence molecular orbitals and the anisotropy in absorption and emission processes. 33,[42][43][44] Using the polarimeter capabilities of the ALS spectrometer, K α emission lines were recorded after resonant photoexcitation at the Cl 1s → 8a 1 resonance for ten different θ angles between incident ( e 1 ) and emitted ( e 2 ) polarization vectors. The experimental spin-orbit ratio were measured from a least-squares fit procedure of the K α emission lines by two Voigt profiles assuming identical emission profiles for the SO doublet 2p 3/2 and 2p 1/2 .…”