With the increasing input power in optical fibers, the dispersion problem is becoming a severe restriction on wavelength division multiplexing (WDM). With the aid of solitons, in which the shape and speed can remain constant during propagation, it is expected that the transmission of nonlinear ultrashort pulses in optical fibers can effectively control the dispersion. The propagation of a nonlinear ultrashort laser pulse in an optical fiber, which fits the high-order nonlinear Schrödinger equation (NLSE), has been solved using the G /G expansion method. Group velocity dispersion, self-phase modulation, the fourth-order dispersion, and the fifth-order nonlinearity of the high-order NLSE were taken into consideration. A series of solutions has been obtained such as the solitary wave solutions of kink, inverse kink, the tangent trigonometric function, and the cotangent trigonometric function. The results have shown that the G /G expansion method is an effective way to obtain the exact solutions for the high-order NLSE, and it provides a theoretical basis for the transmission of ultrashort pulses in nonlinear optical fibers.