Traffic and industry noise have been considered the most
disturbing
pollutants that induce severe health hazards to humans. Porous materials
are commonly used for sound-mitigating applications; however, realizing
high elasticity and sound-absorption ability at low frequencies has
remained a great challenge. Herein, we report a strategy to create
gradient-structured ultralight weight and elastic polymer-based fibrous
aerogels by layer-by-layer assembly of polymer micro- and nanofibers
in different combinations, utilizing step-by-step directional freezing
and freeze-drying methods. This approach allowed us to integrate poly(ethylene
terephthalate) microfibers (MF) and polyvinylidene fluoride nanofibers
(NF) in different combinations, and the combination with MF/(MF and
NF blend) MNF/NF units shows the best noise reduction coefficient
of 0.66. Compared to the individual aerogels of MF, MNF, and NF, the
gradient-structured fibrous aerogels show a better sound-absorption
ability at low frequencies. The gradient-structured fibrous aerogels
exhibit ultralightweight, elasticity, and good mechanical properties.
The successful fabrication of these fascinating structures may provide
innovative prospects for the utilization of used plastics for the
production of low-frequency noise absorbers.