Excess Enthalpies of Ketone + Alkanol at the Temperature 298.15 K

Excess molar enthalpies of R-fenchone+propan-1-ol or +propan-2-ol. Modeling with COSMO-RS and UNIFAC

“…Referring to the higher values of excess enthalpies determined when R-fenchone is mixed with propan-2-ol instead of propan-1-ol, they agree with the usual behavior of mixtures with propanol isomers [23][24][25][26]. This behavior would suggest a greater hydrogen bonds breaking extent in the case of propan-2-ol compared to propan-1-ol because it is known that the enthalpy is higher for the hydrogen bond in propan-1-ol than in propan-2-ol [27].…”

Extension of polar GC-SAFT to systems containing some oxygenated compounds: Application to ethers, aldehydes and ketones

“…Although ethers, aldehydes and ketones are not self-associating compounds, there is a cross-association interaction between H (of the group hydroxyl of alcohol) and O (of functional group CO, O or CHO of oxygenated compounds). This association was evidenced by measurements of excess enthalpy and/or volume (mixtures alcohol + ether [76,77], methanol and ketone, methanol and diethylether [78]), by neutron diffraction (Ceccarelli et al [79] Table 7 Results of predictions for binary cross-associating mixtures using the three versions of polar GC-SAFT.…”

Thermo-Acoustical and Excess Thermodynamic Studies of Ternary Liquid Mixtures of Substituted Benzenes in Aqueous Mixed Solvent Systems at 303.15, 308.15 and 313.15 K

“…Since alkanols are liquids which are associated through hydrogen bonding and in the pure state, they exhibit an equilibrium between multimer and monomer species. Further, when the substituted benzenes such as Nitrobenzene is mixed with 1-heptanol, the NO2 group can interact with OH group [37,38]. The aromatic derivatives set up on interaction between the -electrons cloud and the hydroxyl group.…”