Excess Molar Enthalpies of Ternary Mixtures for Propanone or Benzene + Aniline + 2-Methyl-1-propanol and of Binary Mixtures for Propanone or Aniline + 2-Methyl-1-propanol at 298.15 K

Abstract

Experimental excess molar enthalpies for the ternary mixtures 2-methyl-1-propanol + aniline + propanone and 2-methyl-1-propanol + aniline + benzene and their constituent binary mixtures 2-methyl-1-propanol + aniline and 2-methyl-1-propanol + propanone at the temperature 298.15 K, measured by using an isothermal dilution calorimeter, are reported. The results have been analyzed using a polynomial equation and the UNIQUAC-associated solution model with binary and ternary parameters.

A Combined Experimental, DFT and Molecular Dynamics Simulation Study of Binary Mixture of Ethylbenzene and Aniline

“…In gasolines, aniline, like ethylbenzene is used as a solvent in the antiknock compound. [5][6][7][8][9] The effects of increasing the concentration of ethylbenzene to aniline at different temperatures and their intermolecular interactions are determined in excess thermodynamic properties such as excess molar volume and viscosity deviations. Examining these interactions experimentally, when combined with theoretical methods such as quantum mechanical calculations and molecular dynamics simulation, can provide researchers with very valuable information.…”

“…Aniline is also used in the production of painkillers such as acetaminophen. In gasolines, aniline, like ethylbenzene is used as a solvent in the antiknock compound [5–9] . The effects of increasing the concentration of ethylbenzene to aniline at different temperatures and their intermolecular interactions are determined in excess thermodynamic properties such as excess molar volume and viscosity deviations.…”