Excess volumes and isentropic compressibilities of binary mixtures of a ketone and acetonitrile

Abstract

°C are known (Table V), the single parameter used for (Na+) represents the solubilities well up to about 1.5 M and within

Excess Volumes of N,N-Dimethylformamide with Ketones at 303.15 K

“…All the ketones were further purified by the methods described by Venkateswarlu and Raman (1985). The purities of the samples were checked by comparing the measured densities of the compounds with those reported in the literature (Dharmaraju et al, 1982;Rao and Reddy, 1985;Rintelene et al, 1937). Densities of pure components were determined with a bicapillary type pycnometer, which offers an accuracy of 2 parts in 10 5 .…”

Ultrasonic studies on binary mixtures of some aromatic ketones with acetonitrile at T=308.15K

“…Garcla and Ortega [12] reported excess viscosity, excess volume and excess free energy of activation at various temperatures for the systems of acetonitrile and alkyl Benzoates. Absood et al [13] studied the binary systems of acetonitrile with several aromatic hydrocarbons and discussed the excess molar volumes and excess enthalpies at T = 303.15 K. Dhamaraju et al [14] evaluated excess volumes and isentropic compressibilities of binary mixtures of ketones and acetonitrile and the negative deviations are attributed to the complex formation.…”

Molecular interactions between amine and cyclic ketones at different temperatures

“…All samples were used without further purification because their purities exceeded 99.0 % as tested by gas chromatography using a flame ionization detector with a packed column. Experimental values such as densities q, viscosities g, and ultrasonic speeds u of the pure liquids are compared with the literature values [7,[17][18][19][20][21] in Table 1 at 298.15 K, and the values are in good agreement.…”