Excess volumes, partial molar and adiabatic compressibilities of binary mixtures of<i>n</i>-alcohols with monoethanolamine

Dean, Rebecca K.; Moulins, Jonathan R.; MacInnis, Amanda; Palepu, R.

doi:10.1080/00319100701824306

Cited by 13 publications

(4 citation statements)

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The average absolute relative deviations (AARD %) of density calculations using eq compared with the literature data of Valtz et al, Tsierkezos et al, and Dean et al for MEA with MeOH, MEG, and IPA binary systems are 0.11 %, 0.13 %, and 0.06 % for 322, 15, and 13 data points, respectively. To our knowledge, no data are available in the literature for MeOH + DGA, MEG + DGA, and IPA + DGA systems, and we have retained the data for the identification of these three systems.…”

Section: Resultsmentioning

confidence: 85%

“…To our knowledge, few authors have reported the experimental densities and derived excess properties for the binary systems of primary amines (monoethanolamine and diglycolamine) in alcoholic solutions (methanol, ethylene glycol, and isopropanol). Tsierkezos and Molinou measured the densities and viscosities of ethylene glycol and monoethanolamine binary mixtures at 293.15 K. Valtz et al obtained the densities of monoethanolamine–methanol from (283.15 to 353.15) K. The densities of isopropanol with monoethanolamine from (298 to 358) K were studied by Dean et al Lee and Lin and Song et al researched the systems formed by monoethanolamine, ethylene glycol, ethanol, 2-propanol, and water.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Densities and Excess Properties of Primary Amines in Alcoholic Solutions

Yang

Wang

et al. 2013

J. Chem. Eng. Data

View full text Add to dashboard Cite

In the present work, experimental values for the densities of primary amines (monoethanolamine and diglycolamine) in alcoholic solutions were studied at atmospheric pressure (97.57 kPa) using an Anton Paar digital vibrating U-tube densimeter (model DMA 5000 M) over the entire composition range from (283.15 to 343.15) K, along with the pure components. The alcoholic solutions investigated included methanol, ethylene glycol, and isopropanol. Excess molar volumes, thermal expansion coefficients, and excess thermal expansion coefficients were calculated using the experimental values. A Redlich–Kister type equation as a function of concentration was fitted with the excess molar volumes for representing the density values of the mixture solutions.

show abstract

Section: Resultsmentioning

confidence: 85%

Section: Introductionmentioning

confidence: 99%

Densities and Excess Properties of Primary Amines in Alcoholic Solutions

Yang

Wang

et al. 2013

J. Chem. Eng. Data

View full text Add to dashboard Cite

show abstract

“…The sample table of the pure materials is indicated in Table . In Table , values of density and speed of sound for dimethylbenzylamine and 1-alkanol are compared with those in the literature. − Densities and speed of sound of pure-state chemicals and binary mixtures at various temperatures are indicated in Table . Literature screening indicates that no density and speed of sound are available for the mentioned binary mixtures.…”

Section: Methodsmentioning

confidence: 99%

Experimental Study and Modeling Using the PFP Theory and the ERAS Model of the Excess Molar Volume and Isentropic Compressibility of Dimethylbenzylamine with Alkanol Mixtures at Different Temperatures

2022

View full text Add to dashboard Cite

In the current study, molecular forces in the binary fluids of dimethylbenzylamine and normal alkanols (1-propanol, 1-butanol, 1-pentanol, and 1-hexanol) were studied at 298.15–318.15 K regarding experimental values of density and speed of sound. Negative values of excess molar volume, V m E, and isentropic compressibility deviation, Δκs, were obtained for all binary mixtures. Findings indicate that an increase in alcohol chain length reduces its interaction with dimethylbenzylamine molecules. The ERAS (Extended Real Associated Solutions) model and the PFP (Prigogine–Flory–Patterson) theory were applied to correlate the excess molar volumes, and the outcomes of the two models indicate that for all binary mixtures, the agreement between two sets of data is acceptable. Experimental density and speed of sound for the above binary mixtures have not been reported in the scientific literature yet.

show abstract

“…The middle fractions are used for the experiment, and 2-phenylethanol (Sigma Aldrich, > 0.995 mole fraction purity) is used without further purification. The purity of the chemicals is verified by comparing the densities of the pure compounds and is reported in Table , along with literature values. − …”

Section: Methodsmentioning

confidence: 99%

Activity Coefficients and Excess Gibbs Energies for Binary Mixtures of N-Methyl-2-pyrrolidone with Some Substituted Ethanols

Reddy

Kumar

Rao³

et al. 2012

J. Chem. Eng. Data

View full text Add to dashboard Cite

Isobaric vapor−liquid equilibrium (VLE) data is determined for the binary mixtures of N-methyl-2-pyrrolidone + aminoethanol, N-methyl-2-pyrrolidone + chloroethanol, and N-methyl-2-pyrrolidone + phenylethanol at 95.3 kPa over the entire composition range using a Swietoslawski type ebulliometer. All three systems investigated show negative deviations from Raoult's law, and none of the binary systems formed azeotropic mixtures. The experimental VLE data of the three binary mixtures are correlated using the Wilson model. The computed vapor phase mole fractions, activity coefficients, and Gibbs energy along with optimum Wilson parameters are presented. The studies indicate that all three binary systems are nonideal liquid mixtures deviating from Raoult's law exhibiting negative values of excess Gibbs energies due to strong intermolecular hydrogen bonding between unlike molecules.

show abstract

Excess volumes, partial molar and adiabatic compressibilities of binary mixtures ofn-alcohols with monoethanolamine

Cited by 13 publications

References 28 publications

Densities and Excess Properties of Primary Amines in Alcoholic Solutions

Densities and Excess Properties of Primary Amines in Alcoholic Solutions

Experimental Study and Modeling Using the PFP Theory and the ERAS Model of the Excess Molar Volume and Isentropic Compressibility of Dimethylbenzylamine with Alkanol Mixtures at Different Temperatures

Activity Coefficients and Excess Gibbs Energies for Binary Mixtures of N-Methyl-2-pyrrolidone with Some Substituted Ethanols

Contact Info

Product

Resources

About