The inherent malleability of 2D magnetism provides access
to unconventional
quantum phases, in particular those with coexisting magnetic orders.
Incidentally, in a number of materials, the magnetic state in the
bulk undergoes a fundamental change when the system is pushed to the
monolayer limit. Therefore, a competition of magnetic states can be
expected in the crossover region. Here, an exchange bias state is
observed at the crossover from 3D antiferromagnetism to 2D ferromagnetism
driven by the number of monolayers in the metalloxene GdSi2. The material constitutes a stack of alternating monolayers of Gd
and silicene, the Si analogue of graphene. The exchange bias manifests
itself as a shift of the hysteresis loop signifying coupling of magnetic
systems, as evidenced by magnetization studies. Two features distinguish
the phenomenon: (i) it is intrinsic, i.e. it is detected in an individual
compound; (ii) the exchange bias field, 1.5 kOe, is unusually high,
which is conducive to applications. The results suggest magnetic derivatives
of 2D-Xenes to be prospective materials for ultracompact spintronics.