1973
DOI: 10.1007/bf01209766
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Exchange interaction between two different atoms at large distances

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1973
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Cited by 17 publications
(9 citation statements)
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“…The Landau-Zener approach combined with the decay model was also applied [28] for the description of resonant quenching of ns and nd states of neon by the Ca(4s 2 ) atom resulting from the nonadiabatic transitions between the ionic and Rydberg-covalent terms of a quasimolecule. Using a similar approach [26,28] and the asymptotic model [39][40][41] for the ionic-covalent coupling, an analytical estimate relating the peak position, n max , in the n-dependence of the ionpair formation cross section and the anion binding energy, |ε|, has been derived [29]. It makes the physical meaning of the semiempirically obtained relationship [25] between the values of n max and |ε| clear.…”
Section: Introductionmentioning
confidence: 99%
“…The Landau-Zener approach combined with the decay model was also applied [28] for the description of resonant quenching of ns and nd states of neon by the Ca(4s 2 ) atom resulting from the nonadiabatic transitions between the ionic and Rydberg-covalent terms of a quasimolecule. Using a similar approach [26,28] and the asymptotic model [39][40][41] for the ionic-covalent coupling, an analytical estimate relating the peak position, n max , in the n-dependence of the ionpair formation cross section and the anion binding energy, |ε|, has been derived [29]. It makes the physical meaning of the semiempirically obtained relationship [25] between the values of n max and |ε| clear.…”
Section: Introductionmentioning
confidence: 99%
“…where s is the surface of integration; see Refs. [12,14,15,31] for more details. Note the wavefunctions Φ are here only the spatial components.…”
Section: A Surface Integral Methodsmentioning
confidence: 99%
“…The splitting ∆U is related to the interaction H ic = Φ i |H|Φ c in the (non-orthogonal) diabatic basis (e.g. [31,32])…”
Section: Theorymentioning
confidence: 99%
“…Hence, regarding it as a localized impurity is justified. Na-Au exchange interaction: When the distance between a 22 Na atom and the 197 Au impurity is of the order of R 0 (the atomic size), there is an exchange interaction between their open electronic s shells [20]. It includes a direct exchange term of strength J d (due to antisymmetrization of the electronic wave functions where electrons do not hop between atoms), and an indirect exchange term of strength J p (due to contribution from polar states, where electrons can hope between atoms).…”
Section: Introductionmentioning
confidence: 99%
“…FIG.5: Direct exchange interaction V d (R) [Eq (19),. dashed purple curve], indirect exchange interaction Vp(R) [Eq (20),. dashed and dotted blue curve] and the total exchange interaction V (R) [Eq (23),.…”
mentioning
confidence: 99%