2013
DOI: 10.1039/c3tc30319e
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Excimer-emitting single molecules with stacked π-conjugated groups covalently linked at the 1,8-positions of naphthalene for highly efficient blue and green OLEDs

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Cited by 61 publications
(32 citation statements)
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“…Meanwhile, the peripheral carbazole moiety will also act as an intermolecular contact platform, adding further stabilization via the weak π-stacking interactions. 22 These types of arrangement may be beneficial for the excimer formation in the solid state. 23 As a comparison, the addition of a tert -butyl group on the anthracene moiety of Cz 9 PhAn forms Cz 9 PhAnt (see Scheme 1 ).…”
Section: Resultsmentioning
confidence: 99%
“…Meanwhile, the peripheral carbazole moiety will also act as an intermolecular contact platform, adding further stabilization via the weak π-stacking interactions. 22 These types of arrangement may be beneficial for the excimer formation in the solid state. 23 As a comparison, the addition of a tert -butyl group on the anthracene moiety of Cz 9 PhAn forms Cz 9 PhAnt (see Scheme 1 ).…”
Section: Resultsmentioning
confidence: 99%
“…But due to the great steric hindrance at C1 site of fluorene, [ 11 ] the last‐step Pd‐catalyzed coupling gave no product. The synthetic failure is an important hint: in previous reports, [ 12 ] the researchers had not met similar difficulty when they introduced D/A units in short spatial distance via coupling reaction, indicating other molecular backbones to hold close D/A units were still somewhat flexible. But in our cases, the bulky and robust spiro‐backbone prevented coupling reaction from happening at the adjacent C1 site.…”
Section: Figurementioning
confidence: 99%
“…In this context, naphthalene‐1,8‐diyl linker units have attracted considerable attention for the synthesis of sterically crowded structures,18 electron transfer through proximal π‐systems,19 and organic light‐emitting diode (OLED) materials based on emission from the excimer state 3a. 20 Most of these studies have focused on dimer structures having a covalent linker at only one side or at the center of the chromophore 9b. In contrast, only a few examples have been reported of cyclic dimer structures linked on either side by two naphthalene‐1,8‐diyl units 21…”
Section: Introductionmentioning
confidence: 99%