Abstract:RbFe 2+ Fe 3+ F6 is an example of an antiferromagnet with charge ordering of the octahedrally coordinated Fe 2+ and Fe 3+ ions. As well as different spin values, Fe 2+ (S = 2) and Fe 3+ (S = 52 ) possess differing orbital ground states with Fe 2+ having an orbital degeneracy with an effective orbital angular momentum of l = 1. The resulting low temperature magnetic structure is non collinear with the spins aligned perpendicular to nearest neighbors (S. W. Kim et al. Chem. Sci. 3, 741 (2012)). The combination … Show more
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