This paper proposes a new approach for the performance analysis of a single-stage solar adsorption refrigeration system with activated carbon-R134a as working pair. Use of artificial neural network has been proposed to determine the performance parameters of the system, namely, coefficient of performance, specific cooling power, adsorbent bed (thermal compressor) discharge temperature, and solar cooling coefficient of performance. The ANN used in the performance prediction was made in MATLAB (version 7.8) environment using neural network tool box.In this study the temperature, pressure, and solar insolation are used in input layer. The back propagation algorithm with three different variants namely Scaled conjugate gradient, Pola-Ribiere conjugate gradient, and Levenberg-Marquardt (LM) and logistic sigmoid transfer function were used, so that the best approach could be found. After training, it was found that LM algorithm with 9 neurons is most suitable for modeling solar adsorption refrigeration system. The ANN predictions of performance parameters agree well with experimental values with R2 values close to 1 and maximum percentage of error less than 5%. The RMS and covariance values are also found to be within the acceptable limits.