We prove exponential convergence to the invariant measure, in the total variation norm, for solutions of SDEs driven by α-stable noises in finite and in infinite dimensions. Two approaches are used. The first one is based on Harris theorem, and the second on Doeblin's coupling argument [10]. Irreducibility, Lyapunov function techniques, and uniform strong Feller property play an essential role in both approaches. We concentrate on two classes of Markov processes: solutions of finite-dimensional equations, introduced in [29], with Hölder continuous drift and a general, non-degenerate, symmetric α-stable noise, and infinite-dimensional parabolic systems, introduced in [32], with Lipschitz drift and cylindrical α-stable noise. We show that if the nonlinearity is bounded, then the processes are exponential mixing. This improves, in particular, an earlier result established in [30] using the weak convergence induced by the Kantorovich-Wasserstein metric.