2013
DOI: 10.1080/0889311x.2013.804817
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Existence of minimum molar volumes (maximum packing densities) in morphotropic series of mixed oxides and fluorides

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Cited by 2 publications
(2 citation statements)
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“…For pyrochlore type tellurate reported as “K 2 GeTeO 6 ”, an even shorter K–K distance of 2.83 Å may be calculated, but this composition is definitely wrong . The reported values of its experimental and calculated density, 4.40 and 4.46 g/cm 3 , respectively, agree only assuming an incorrect Z of 7.…”
Section: Resultsmentioning
confidence: 94%
“…For pyrochlore type tellurate reported as “K 2 GeTeO 6 ”, an even shorter K–K distance of 2.83 Å may be calculated, but this composition is definitely wrong . The reported values of its experimental and calculated density, 4.40 and 4.46 g/cm 3 , respectively, agree only assuming an incorrect Z of 7.…”
Section: Resultsmentioning
confidence: 94%
“…4, the formula volumes of trigonal MSb 2 O 6 (except for M = Cu) have an excellent correlation with the ionic radii of M 2+ , and for the five new phases, they are 2-3% larger than those for the stable trirutile-type phases although all coordination numbers are the same. 4 presents an additional example of a morphotropic series where substitution of a larger cation (herein, Co 2+ in CoSb 2 O 6 ) by an even larger cation (herein, Mn 2+ or Cd 2+ ) leads to less dense structure types, 28 opposite to the widely assumed homology rule. 4 presents an additional example of a morphotropic series where substitution of a larger cation (herein, Co 2+ in CoSb 2 O 6 ) by an even larger cation (herein, Mn 2+ or Cd 2+ ) leads to less dense structure types, 28 opposite to the widely assumed homology rule.…”
Section: Structural Characterizationmentioning
confidence: 99%