Exo- or endo-1<i>H</i>-pyrazole metal coordination modulated by the polyamine chain length in [1 + 1] condensation azamacrocycles. Binuclear complexes with remarkable SOD activity

Bonastre-Sabater, Irene; Lopera, Alberto; Martínez-Camarena, Álvaro; Blasco, Salvador; Doménech-Carbó, Antonio; Jiménez, Hermas R.; Verdejo, Begoña; García-España, Enrique; Clares, M. Paz

doi:10.1039/d4dt01236d

Dalton Trans.

2024

DOI: 10.1039/d4dt01236d

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Exo- or endo-1H-pyrazole metal coordination modulated by the polyamine chain length in [1 + 1] condensation azamacrocycles. Binuclear complexes with remarkable SOD activity

Irene Bonastre-Sabater,

Alberto Lopera,

Álvaro Martínez-Camarena

et al.

Abstract: Increasing the polyamine chain length changes the binding mode of pyrazole from exo to endo in Cu2+ complexes of pyrazolacyclophanes, leading to outstanding SOD activity.

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Exo- or endo-1H-pyrazole metal coordination modulated by the polyamine chain length in [1 + 1] condensation azamacrocycles. Binuclear complexes with remarkable SOD activity

Abstract: Increasing the polyamine chain length changes the binding mode of pyrazole from exo to endo in Cu2+ complexes of pyrazolacyclophanes, leading to outstanding SOD activity.

Cited by 0 publications

References 100 publications

No citations

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