Exothermic character of the dissociated ions in binary phenol amine mixtures

Huyskens, P.; Felix, N.; Neven, L.

doi:10.1016/0378-4487(80)80014-8

Advances in Molecular Relaxation and Interaction Processes

1980

DOI: 10.1016/0378-4487(80)80014-8

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Exothermic character of the dissociated ions in binary phenol amine mixtures

P. Huyskens

N. Felix

L. Neven

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1980

1985

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Cited by 2 publications

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Endothermic or exothermic character of the dissociation of ion pairs

Huyskens

1980

Bulletin des Soc Chimique

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In the gaseous phase the dissociation enthalpy AHd of ion pairs is always positive. In the liquid phase the polarization of the molecules of the medium around the separate ions decreases the dissociation enthalpy and in some cases renders it negative. Other factors which influence the enthalpy of dissociation are the formation of hydropen bonds or charge transfer bonds between the ions o r between the ions and the solvent molecules. An equation based on the theories of Denison and Ramsey and o f Gilkerson which takes these effects into account is : AHd = (eZN/aD) (confronted with the data of the literature.

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Endothermic or exothermic character of the dissociation of ion pairs

Huyskens

1980

Bulletin des Soc Chimique

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Thermodynamic properties of associated solutions

Marsh¹,

Köhler²

1985

Journal of Molecular Liquids

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Exothermic character of the dissociated ions in binary phenol amine mixtures

Cited by 2 publications

References 7 publications

Endothermic or exothermic character of the dissociation of ion pairs

Endothermic or exothermic character of the dissociation of ion pairs

Thermodynamic properties of associated solutions

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