Hydrofluoroolefins (HFOs) are currently
being developed to replace
hydrofluorocarbons (HFCs) with high global warming potential (GWP)
in air-conditioning and refrigeration systems. The development of low-GWP HFOs requires detailed
knowledge of the key thermophysical properties of these refrigerants
with commonly used lubricating oils at varying operational conditions.
The liquid-phase dynamic viscosity and density data for a synthetic
polyol ester lubricating oil (ISO VG 32) saturated with compressed
2,3,3,3-tetrafluoropropene (R-1234yf) and trans-1,3,3,3-tetrafluoropropene
(R-1234ze(E)) were measured over temperatures ranging from 248.15
to 348.15 K and pressures up to 0.6 MPa. The liquid compositions for
the viscosity and density data were calculated using previously measured
vapor–liquid equilibrium data and models. The liquid phase
viscosity decreased significantly with increased composition of the
refrigerant. The experimental viscosity and density obtained for each
refrigerant and lubricating oil system were successfully correlated
using Redlich–Kister expansions for excess volume and “excess
viscosity”. From the data and modeling, the kinematic viscosities
were calculated and Daniel plots were generated. In addition, the
previously measured diffusivities for each HFO/ISO VG 32 lubricating
oil system were well correlated with the reported experimental viscosity
data according to the Stokes–Einstein theory.