Efficient and economical purification of nitrous oxide (N 2 O), one of the most abundant greenhouse gases, is urgently needed to prevent global warming, especially from exhaust emissions produced during adipic acid production. This study investigates the N 2 O thermal decomposition process via high-temperature incineration (800−1400 °C), as well as the effects of oxygen (O 2 ) and methane (CH 4 ) on deN 2 O efficiency and nitrogen selectivity. Under sufficient reaction conditions, deN 2 O efficiency reached 100% at ∼1000 °C. The introduction of CH 4 was found to significantly enhance deN 2 O efficiency, with the addition of 5% CH 4 resulting in complete N 2 O removal at <900 °C. Additionally, the influences of O 2 and CH 4 on the products nitric oxide and nitrogen dioxide (NO 2 ) were analyzed via temperature-programmed reaction monitoring. Combined with the energy barriers obtained from density functional theory calculations, the reaction pathway network of N 2 O decomposition with and without CH 4 was established. Moreover, the reaction rate equation for the crucial byproduct NO 2 was derived from the elementary steps in the reaction network.