Devolatilization
and fragmentation are important physical phenomena
occurring during solid fuel chemical looping combustion (CLC). Primary
fragmentation during devolatilization strongly affects the rate of
fuel conversion, emissions, and fine particulates generation in a
fuel reactor of a fluidized bed CLC unit, thus forming a critical
design input. The present study focuses on investigating the primary
fragmentation behavior of large coal and biomass (wood) particles
during the devolatilization phase of CLC. Three types of coals (two
Indian coals, one Indonesian coal) and one type of Casuarina wood
of three sizes in the range of 8–25 mm, at different fuel reactor
bed temperatures (800, 875, and 950 °C) are studied for primary
fragmentation. Iron ore with 64% Fe is used as the oxygen carrier
bed material, with steam as the fluidizing medium in the fuel reactor.
The fragmentation behavior is expressed in terms of the number of
fragments, fragmentation index, frequency of fragmentation, and particle
size distribution of fragments at different residence times of coal
during devolatilization in the fuel reactor. Under the conditions
of study, the number of fragments increases with an increase in particle
size and temperature, for all fuels studied. Also, it is found that
the number of fragments increases with the decrease in compressive
strength of both coal and biomass particles. The Indian coals are
found to fragment in the earlier stages of devolatilization, while
the Indonesian coal and the biomass particles begin to fragment in
the later stages of devolatilization. The maximum fragmentation index
is found with Indian coal - IC1, which has the highest fixed carbon
content among the fuels studied, and the least value is observed in
biomass. Different modes of fragmentation exhibited by each fuel type
is discussed. Indian coals do not show any volumetric changes as such,
whereas Indonesian coal indicates some degree of volumetric expansion.