“…Typically, in order to measure the sorption kinetics, a sample of material is placed in a climatic chamber supposed to be able to maintain the air around the sample at a given value of RH, i.e., n ∞ , while the material has been prepared under a different RH, i.e., n 0 . ,,,− The sorption dynamics of the material is then expected to depend on n ∞ and n 0 , and it is described through the relative variation of the sample mass in time. In that case, it is implicitly assumed that there is negligible air flow and, for the relevance of the theoretical analysis, that the boundary condition, i.e., the RH along the surface of the sample, remains equal to the ambient one, i.e., n ∞ .…”