Catalytic
aquathermolysis in situ upgrading and reducing the
viscosity of heavy oil in the reservoir remarkably enhances the recovery
and is considered as a promising technology. However, the low catalytic
efficiency and inferior dispersity in both water and oil limit its
applications. In the present work, spherical polymer brush nanocatalysts
were synthesized, in which nano-TiO2 is the core and poly(vinyl
imidazole) (PVI)-loading nickel cations are polymer brushes. The chemical
characteristics, polymer-grafting content, nickel-loading content,
and morphology of as-prepared catalysts were characterized by infrared
(IR) spectroscopy, thermogravimetric analysis, inductively coupled
plasma optical emission spectrometry, scanning electron microscopy,
and transmission electron microscopy. The polymerization degree of
PVI was analyzed by proton nuclear magnetic resonance (1H NMR) spectra. The effects of the nickel-loading content, catalytic
conditions, and hydrogen donor on the viscosity of heavy oil were
studied. The results show that the heavy oil is catalytically cracked
by the synthesized catalysts, which leads to the reduction of oil
viscosity. The viscosity reduction is enhanced by the increase of
the nickel-loading content, catalytic temperature, dosage of catalyst,
and hydrogen donor. The rheological behaviors in terms of flow curve,
thixotropy, viscoelasticity, and time dependence of cracked oil were
studied. To explore the cracking mechanism, the four compositions
of heavy oil before and after aquathermolysis were compared. The extracted
asphaltenes and resins were further analyzed by elemental analysis, 1H NMR spectra, and IR spectroscopy. The organic compounds
in reacted water were characterized by gas chromatography–mass
spectrometry. It is found that the content of light saturates is much
increased after aquathermolysis, along with the distinct decrease
of resins. From the structure change of resins, such as the decrease
of hydrogen/carbon and methylene/methyl ratios and increase of aromaticity
and aromaticity condensation, the increased light saturates are due
to the dissociation of alkyl side chains in resins. In addition, the
aromaticity and aromaticity condensation in asphaltenes are found
decreased, which is because of the fragmentation and depolymerization
of large aromatics. Meanwhile, the loss of oxygen in both asphaltenes
and resins is connected with the phenols found in the reacted water,
indicating the breakage of the C–O bond and heteroaromatic
ring-open reaction in both asphaltenes and resins during aquathermolysis.