Experimental and Theoretical Study of Water Retention Effects on Elastic Properties of Opalinus Shale

Abstract

Understanding of shales elastic properties behaviour with saturation changes is important for geological storage of nuclear waste, CO2 sequestration as well as for development of conventional and unconventional shale oil and gas reservoirs. Existing data describing effects of saturation on elastic properties of shales are sparse and contradictory. To improve understanding of the effects of changing water content on elastic properties in shales, we conduct an experimental study on Opalinus shale samples. We measure vertical and horizontal ultrasonic P-and S-wave velocities of the same set of samples with controlled water content. The measured velocities are used to calculate components of elastic stiffness tensor in the shale at different saturations assuming its vertical transverse isotropy. Obtained results show increasing C11 and decreasing C33 with drying of the samples. Moreover, we observe 80% and 60% increase of shear moduli C44 and C66, respectively, with reduction of the water content from 5.5% weight in the preserved state to 0.3%. Conventional rock physics models are not designed to explain the observed dynamics. Here we perform a theoretical investigation of the influence on the shale moduli of following factors: (1) mechanical softening of the rock with the decrease of water saturation; (2) shrinkage of clay leading to reduction of porosity; (3) chemical hardening of clay particles; and (4) enhancing stiffness of contacts due to removing of water between clay particles.