This paper presents extensive experimental characterization and empirical modelling of 802.11 temporal behavior. A detailed characterization of 802.11b/g/n homogeneous and heterogeneous network traffic patterns is featured, including idle time distribution and channel utilization. A complete modelling of 802.11 networks in the 2.4 GHz Industrial, Scientific, and Medical band is also presented. Such information can assist the development of other wireless technologies aiming to utilize the crowded Industrial, Scientific, and Medical band more efficiently and to achieve enhanced wireless coexistence. In this work, models are derived for both homogeneous and heterogeneous 802.11 network idle time distributions. Also presented is a case study utilizing 802.15.4 ZigBee transmitter packet size that was adaptively modified based on channel idle time distribution. Results demonstrate superior ZigBee performance and significant enhancement in throughput.