In this work, lab-scale cold fluidization equipment is designed and constructed to investigate the mixing and segregating phenomena of binary fluidized beds. The focus of the investigation is carbon reduction with the fluidized bed technology-based Chemical Looping Combustion (CLC). Nowadays, aspiration to carbon reduction focuses on the solid fuels. Therefore, it is of great importance to integrate the benefits of CLC technology with the use of solid fuels. The measurements of fuel particles in the fluidized bed are extended from the homogeneous and spherical shape to the inhomogeneous, non-spherical shape. During the tests, an iron-based oxygen carrier (OC) for chemical looping combustors is examined with different particle sizes. In addition, the tests included the examination of three different fuel samples (crushed coal, agricultural pellet, and Solid Recovered Fuel (SRF)), which can be utilized in chemical looping combustion with In-situ gasification. The experiments are carried out using the bed-frozen method. With this method, the vertical concentration of active particles could be measured. The results show that the particle size of the oxygen carrier does fundamentally influence its vertical placement, and the non-spherical character of most alternative fuels must also be considered for optimal reactor design.