This research is to identify how much toxic combustion gases are produced from Korea standardized real fire test (Class A&B) by using Room Corner Tester (RCT) and how much those gases are possibly dangerous to testing personnel by estimating the level of carboxyhemoglobin (% COHb). It is confirmed that testing personnel can be affected as more than 40% COHb from Class A 9th and 10th rating in respiration minute volume (RMV) 2 and from Class A 5th to Class A 10th rating in RMV 3 during the time for initial three minutes. Also, in the case of Class B real fire tests, although it is considered rather safe for the initial 1 minute, testing personnel can be affected as more than 20% COHb from Class B 16th to 20th rating in RMV 3 during total test time. Currently, the Korea standard is only focusing on the protection measures against the heat, but the it is neglecting the protection measures against toxic combustion gases. Therefore, according to this study, it is strongly recommended that testing personnel should wear a self-contained breathing apparatus, or the equivalence depending on the real fire test rating.