In this study, the authors have presented
a numeric model (NM)
for application to naphthalene (C10H8) conversion
via ionization reaction in a microwave air plasma torch. The NM has
included a pressure-independent enhanced electron energy distribution
function (EEDF) and cross-section calculation, enhanced by a new formula
of phase shift determination. Based on the validated NM, electron
density n
e
and O
2
+, O
–, C
10
H
8, N
2, and O
2 particles densities were calculated, as well
as the conversion rate of C10H8 molecules was
predicted. The predicted results showed that the ionization impact
on C10H8 molecules conversion has not exceeded
0.81 × 10–10%. Based on the calculated collision
cross-section of each species (O2, N2, and C10H8) of carrier gas, the authors suggested using
cubic polynomial approximations of the cross-section curves with R-Square
(COD) parameter R
2 = 99%. MW power increasing
in the range 1.75–20 kW has raised the electron density in
the range (0.5–4.5) × 1012 m–3. The maximal effect of electron density decreasing with pressure
increasing was simulated at values of MW power greater than 7.5 kW.
Herewith, pressure increasing and MW power increasing have not had
any significant effect on the average electron energy.