CO2 gas is one of the most effective injectants
for
enhanced oil recovery (EOR). New injection technique like polymer-alternating-gas
(PAG) is aimed at further improving oil recovery efficiency from conventional
gas injection; however, the oil recovery mechanism and fluid interactions
underlying PAG have not yet been studied at a microscopic level. This
study conducts the first micromodel study to better understand the
relevant mechanisms and interactions of PAG at high pressure and temperature.
Traditional methods, including water, polymer, CO2, and
water-alternating-gas (WAG), are also investigated and compared with
PAG. The experiments use a rock-shaped micromodel glass and decane
to represent reservoir oil. An oil miscibility test is performed by
injecting CO2 into a micromodel prefilled with decane at
a temperature of 40 °C and pressure varying within 70–90
bar. Oil miscibility, as determined by the disappearance of an oil-CO2 interface, is achieved at a pressure of 90 bar. When comparing
the WAG and PAG methods, the PAG method is more effective in producing
additional oil recovery of up to 6%. This is due to the polymer’s
better displacement efficiency, stronger gas flow diversion effects,
and slightly higher miscibility level. The observed oil recovery mechanisms
are oil displacement, miscibility, flow diversion, oil swelling, and
CO2 dissolution and diffusion. This study proposes a simple
miscibility test, proves the effectiveness of the PAG method, and
demonstrates various phenomena related to oil recovery processes.
Integrating those effects and new injection strategies in the simulation
study will benefit the CO2-EOR field design.