High temperature is recognized as one of the extreme environments in the application of shotcrete which significantly deteriorate the performance of shotcrete. This paper reviews the mechanical properties and microstructure of shotcrete under high temperature. First of all, this paper reviews the cause of formation of high ground temperature. Based on these causes, the author establishes a heat transfer model with a spiral shape by introducing a multidimensional morphological formula into the heat conduction process. Then, the paper reviews the influence of high temperature on the mechanical and micro properties of shotcrete, the cooling technology under high temperature, and the optimization research technology of shotcrete. The author discusses the influence of high temperature on the thermal parameters and the deformation of shotcrete from the perspective of thermodynamics. Multiple studies have shown that the irregular movement and disorderly overlapping of molecules in the shotcrete caused by the high temperature environment result in the premature termination of the hydration reaction of cement in shotcrete. Finally, the author suggests the challenges of high-temperature shotcrete in term of the process structure, performance optimization, and application in special engineering fields. The research in this paper intends to give guidance to those conducting shotcrete research under high temperature, and to promote the further development of shotcrete technology.