“…By increasing the fluence over the ablation threshold, the saturation of the produced plasma density allows the increase of the ions and electrons temperatures [7]. Because of the transient features of the plasma created by LIP, optical emission spectroscopy (OES) technique with time and space resolution is especially used to obtain information about the behavior of the created plasma species in space and time as well as the dynamics of the plasma evolution [8][9][10]. The ratio for intensity of two lines of the same species of ionization stage Z in the emission spectrum of the target ablated b laser is expressed as: where I 1 is the line intensity from the k-i transition (arbitrary unit), I 2 is that from the nm transition (arbitrary unit), is the wavelength from the k-i transition (nm), is the wavelength from the n-m transition (nm), is the transition probability from the k-i transition (s -1 ) , is the transition probability from the n-m transition (s -1 ), is the statistical weight of the k state, is the statistical weight of the n state, is the energy of the k state (eV), is the energy of the n state (eV), k B is the Boltzmann constant 1.38x10 -23 J.K -1 , and T e is the electron temperature (eV).…”