Kerosene-based ferrofluid
(FF) loaded with multiwalled carbon nanotubes
(MCNTs) is prepared and characterized to enhance heat conduction and
furthermore for potential application in high-speed ferrofluid seals.
The present study investigates kerosene-based ferrofluid loaded with
MCNTs for the thermal conductivity and magnetization behaviors by
varying temperature, weight fractions of MCNTs, and functional groups
of MCNTs. The thermal conductivity is then measured by using a transient
hot wire method, and magnetization behaviors are measured by using
vibrator sample magnetometers. Microstructures among MCNTs and microstructures
between MCNTs and magnetic nanoparticles in nanofluids are analyzed
by optical microscopy and transmission electron microscopy. Experiments
are carried out in the temperature range of 20–50 °C,
MCNT weight fraction range of 0–1% for kerosene-based ferrofluid
loaded with pristine MCNTs (p-MCNTs), MCNTs functionalized with carboxylic
groups (MCNTs-COOH), and MCNTs functionalized with hydroxyl groups
(MCNTs-OH). Results show that thermal conductivity and magnetization
of FF + MCNTs nanofluids decrease with the increase in temperature.
The addition of MCNTs increases the thermal conductivity and decreases
the magnetization of the original ferrofluid, especially in the FF
+ p-MCNTs nanofluids. Furthermore, the addition of 1 wt % p-MCNTs
increases the thermal conductivity and decreases the magnetization
of the original ferrofluid by 12.47 and 7.73%, respectively. Moreover,
the FF + 1 wt % p-MCNTs nanofluid can be stable for at least eleven
weeks, which might be basically applied to high-speed ferrofluid seals.