Experimental investigation on hydrated salt phase change material for lithium-ion battery thermal management and thermal runaway mitigation

Zhi, Maoyong; Fan, Rong; Zheng, Lingling; Yue, Shan; Pan, Zhiheng; Sun, Qiang; Liu, Quanyi

doi:10.1016/j.energy.2024.132685

Energy

2024

DOI: 10.1016/j.energy.2024.132685

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Experimental investigation on hydrated salt phase change material for lithium-ion battery thermal management and thermal runaway mitigation

Maoyong Zhi,

Rong Fan,

Lingling Zheng

et al.

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Cited by 3 publications

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Effect of Deuteration on Raman Scattering in Single Crystals of Potassium Alum

Avakyants,

Skrabatun,

Pyatyshev

2024

J Raman Spectroscopy

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Raman spectra of KAl(SO4)2·12H2O and KAl(SO4)2·12D2O crystals in the range of 10–4000 cm−1 were experimentally obtained and studied. An increase in the number of sulfate ions, oriented by oxygen atoms towards the K+ ion, was detected upon deuteration of the sample. Low‐intensity Stokes components ν = 2485 cm−1 (ν = 1820 cm−1 for the deuterated crystal) were recorded, which indicates the formation of hydrogen bonds O–H•••SO42− (O–D•••SO42−), where the donors are water molecules of the [Al(H2O)6]3+ complex and the oxygen atoms of the sulfate ion act as acceptors. The decrease in the wavenumbers of internal vibrations of the sulfate ion during deuteration was explained by an increase in the strength of hydrogen bonds. The results obtained indicate the direct influence of deuteration on the degree of initial disordering of sulfate ions and on the stability of the crystal structure of potassium alum.

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Effect of Deuteration on Raman Scattering in Single Crystals of Potassium Alum

Avakyants,

Skrabatun,

Pyatyshev

2024

J Raman Spectroscopy

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Investigation on the polyethylene glycol based composite phase change materials with coating flame-retardant for battery thermal management

Wang,

Deng,

et al. 2025

Case Studies in Thermal Engineering

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Salt hydrates in renewable energy systems: A thorough review

Ghafurian,

Elmegaard,

Weinberger

et al. 2024

Energy

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Experimental investigation on hydrated salt phase change material for lithium-ion battery thermal management and thermal runaway mitigation

Cited by 3 publications

References 49 publications

Effect of Deuteration on Raman Scattering in Single Crystals of Potassium Alum

Effect of Deuteration on Raman Scattering in Single Crystals of Potassium Alum

Investigation on the polyethylene glycol based composite phase change materials with coating flame-retardant for battery thermal management

Salt hydrates in renewable energy systems: A thorough review

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