Accurate evaluation
of the shell elastic modulus of microcapsules
is of great significance to understanding their performance during
production, processing, and applications. In this work, microcompression
was employed to investigate the elastic behaviors of a single microcapsule.
It was modeled as a microsphere with a core–shell structure
compressed between two rigid plates. Based on the assumption that
the contact pressure between the microsphere and plates obeys parabolic
distribution, a microcompression method derived from the Reissner’s
theory and the modified Hertz contact theory was established to evaluate
the shell elastic modulus. Applications were carried out on poly(methylmethacrylate)
(PMMA) microcapsules containing n-octadecane. The
average elastic modulus of PMMA shells measured by the proposed microcompression
method agrees well with that of the bulk PMMA sample. Furthermore,
the elastic modulus of PMMA shells was found to have size dependence
on the diameter of the microcapsules. Finally, finite element models
combined with the newly proposed method were constructed to accurately
predict the microcompression behaviors of microcapsules with different
sizes.