In the past century, precast reinforced concrete has become the most widely used construction material in infrastructure engineering, especially for long-span structures. Nowadays, a growing research area concerns the assessment of concrete strength degradation due to environmental exposure and reinforcement corrosion. This paper reports an experimental campaign on some prefabricated concrete elements that were exposed to atmospheric agents for approximately 20 years. The campaign took the uncommon opportunity to access the full inspection and sampling of rebar. The included activities had different invasiveness and encompassed inspections, core sampling, corrosion potential mapping, compressive strength tests, as well as neutralization depth assays on cored surfaces, on chisel-split surfaces, and on drilling powders. The results bring together a global diagnostic picture of very limited degradation and of elements that are fully able to attend their design service life; the latter is estimated to be considerably higher than 20 years and to exceed 75 years if the concrete mix does not show quality issues. Results also permit drawing considerations on a hierarchy of diagnostic reliability in the evaluation of RC degradation, in which concrete core sampling plays the role of golden standard.