2011
DOI: 10.1103/physreva.84.034501
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Experimental isotope shifts of the 5 2S1/2state and low-lying excited states of Rb

Abstract: By combining a recent precise measurement of the ionization energy of 87 Rb with previous measurements of the ground-state hyperfine structure and ionization energy of 85 Rb, an accurate value for the 85 Rb-87 Rb isotope shift of the 5 2 S 1/2 ground state can be determined. In turn, comparison with additional spectroscopic data makes it possible to evaluate isotope shifts for the low-lying excited states, which are accurate in most cases to about 1 MHz. For the 5 2 S 1/2 and 5 2 P 3/2 states, the specific mas… Show more

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Cited by 9 publications
(5 citation statements)
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“…III a comparison between the literature values and the newly determined values is shown. The total isotope shifts were found to be 41.935(60) MHz for the 6P 3/2 isotopes and 41.237(62) MHz for the 6P 1/2 isotopes, which agree well with the literature values [26,27]. With the determined hyperfine splitting values, the magnetic dipole constant A and the electric quadrupole constant B can be calculated for the 5S → 6P transitions.…”
Section: Discussionsupporting
confidence: 86%
“…III a comparison between the literature values and the newly determined values is shown. The total isotope shifts were found to be 41.935(60) MHz for the 6P 3/2 isotopes and 41.237(62) MHz for the 6P 1/2 isotopes, which agree well with the literature values [26,27]. With the determined hyperfine splitting values, the magnetic dipole constant A and the electric quadrupole constant B can be calculated for the 5S → 6P transitions.…”
Section: Discussionsupporting
confidence: 86%
“…The data of the hyperfine splittings and isotope shifts for Rb [14,19,20], In [13,15], K [14,21,22], and Ga [13,15,23] are combined with our measurements to calculate the center-of-mass frequencies.…”
Section: Absolute Frequenciesmentioning
confidence: 99%
“…The line at λ7800 Å of interest here is a hyperfine multiplet produced by the transition 2 S 1/2 − 2 P 3/2 . The isotopic shifts δ = E 85 − E 87 , that is, the energy difference for a given level between the level for 85 Rb and 87 Rb are: δ( 2 S 1/2 ) = 164.35 MHz, and δ( 2 P 3/2 ) = 86.31 MHz, respectively (Aldridge et al 2011). The hyperfine effective Hamiltonian was parametrised in terms of the magnetic-dipole and electricquadrupole hyperfine structure constants.…”
Section: Zeeman Broadeningmentioning
confidence: 99%