This paper presents the results of interferometry of flames and combustion properties by conducting extensive experimental measurements and numerical simulations of a syngas flame in an intersecting burner setup. The experiments were performed to analyze the effects of key parameters on the flame structure and the temperature field of the intersecting slot burners in a dual-flame syngas combustion setup using the Mach−Zehnder interferometry technique. The Reynolds number, equivalence ratio, intersecting angle of burners, and jet-to-jet spacing between the burners were studied and validated with an acceptable accuracy. It was shown that, although an increasing Reynolds number from 100 to 200 does not change the maximum flame temperature more than 125 K, it has a significant influence on the flame structure. In addition, the maximum temperature is directly related to the intersecting angle and has an inverse relation with the equivalence ratio and jet-to-jet spacing. The maximum temperature of 2211 K was observed for θ = 100°. Results from the numerical simulations confirmed the data obtained from the interferometry and showed that NO x formation increases as the maximum observed temperature increases.