This paper pays attention to the broader interest of freezing water droplets in mesotronics, particularly to their use as a new all-optical device platform. Here, we show that a freezing mesoscale water droplet with a low Bond number can behave as fully biocompatible natural microlense to form a photonic hook for application in a tunable temperature-controlled optical switch. We first introduced and demonstrated the basic concepts of an optical switch without changes in the wavelength of illumination of a particle or any moving parts being involved. The principle of the operation of the switch is based on the temperature-induced phase change inside the water droplet’s refractive index. The simulation results show that the optical isolation of switched channels for an optical switch with linear dimensions of about 15 λ3 based on a freezing water droplet can reach 10 dB in the process of temperature variation at a fixed wavelength. The use of freezing mesoscale droplets acting as a time-domain photonic hook generator open an intriguing route for optical switching in multifunctional green electronics tools for sensing, integrated optics and optical computers.